If you've ruled out the cooling system (impeller, plugged rad, low coolant etc). Then it has to be excessive heat generation. Excessive heat from a lean condition - air leak somewhere. I'd leak test it before you pull the head. You need the head on to leak test it anyways, so leave it on and pressurize it. My guess is that it won't be the head. Typically you'd get coolant out the overflow if it was.